Publications

Export 59 results:
Sort by: Author Title [ Type  (Asc)] Year
Journal Article
Faustino, B. M. M., D. Gomes, J. Faria, T. Juntunen, G. Gaspar, C. Bianchi, A. Almeida, A. C. Marques, I. Tittonen, and I. Ferreira, "CuI p-type thin films for highly transparent thermoelectric pn modules", Sci Rep, vol. 8, issue 1, pp. 6867-6867, 2018. AbstractDOI

Developments in thermoelectric (TE) transparent p-type materials are scarce and do not follow the trend of the corresponding n-type materials – a limitation of the current transparent thermoelectric devices. P-type thermoelectric thin films of CuI have been developed by three different methods in order to maximise optical transparency (>70% in the visible range), electrical (σ = 1.1 × 104 Sm−1) and thermoelectric properties (ZT = 0.22 at 300 K). These have been applied in the first planar fully transparent p-n type TE modules where gallium-doped zinc oxide (GZO) thin films were used as the n-type element and indium thin oxide (ITO) thin films as electrodes. A thorough study of power output in single elements and p-n modules electrically connected in series and thermally connected in parallel is inclosed. This configuration allows for a whole range of highly transparent thermoelectric applications.

Cristovão, A. F., D. Sousa, F. Silvestre, I. Ropio, A. Gaspar, C. Henriques, A. Velhinho, A. C. Baptista, M. Faustino, and I. Ferreira, "Customized tracheal design using 3D printing of a polymer hydrogel: influence of UV laser cross-linking on mechanical properties", 3D Print Med, vol. 5, pp. 12, 2019.
Mendes, M. J., A. Araújo, A. Vicente, H. Águas, I. Ferreira, E. Fortunato, and R. Martins, "Design of optimized wave-optical spheroidal nanostructures for photonic-enhanced solar cells", Nano Energy, vol. 26, pp. 286-296, 2016. AbstractDOI

The interaction of light with wavelength-sized photonic nanostructures is highly promising for light management applied to thin-film photovoltaics. Several light trapping effects come into play in the wave optics regime of such structures that crucially depend on the parameters of the photonic and absorbing elements. Thus, multi-parameter optimizations employing exact numerical models, as performed in this work, are essential to determine the maximum photocurrent enhancement that can be produced in solar cells.

Generalized spheroidal geometries and high-index dielectric materials are considered here to model the design of the optical elements providing broadband absorption enhancement in planar silicon solar cells. The physical mechanisms responsible for such enhancement are schematized in a spectral diagram, providing a deeper understanding of the advantageous characteristics of the optimized geometries. The best structures, composed of TiO2 half-spheroids patterned on the cells' top surface, yield two times higher photocurrent (up to 32.5 mA/cm2 in 1.5 µm thick silicon layer) than the same devices without photonic schemes.

These results set the state-of-the-art closer to the theoretical Lambertian limit. In addition, the considered light trapping designs are not affected by the traditional compromise between absorption enhancement versus current degradation by recombination, which is a key technological advantage.

Baptista, A. C., A. M. Botas, A. P. C. Almeida, A. T. Nicolau, B. P. Falcão, M. J. Soares, J. P. Leitão, R. Martins, J. P. Borges, and I. Ferreira, "Down conversion photoluminescence on PVP/Ag-nanoparticles electrospun composite fibers", Opt. Mater., vol. 39, pp. 278-281, 2015. AbstractDOI

The influence of Ag nanoparticles (Ag NPs) on the luminescence of electrospun nonwoven mats made of polyvinylpyrrolidone (PVP) has been studied in this work. The PVP fibers incorporating 2.1–4.3 nm size Ag NPs show a significant photoluminescence (PL) band between 580 and 640 nm under 325 nm laser excitation. The down conversion luminescence emission is present even after several hours of laser excitation, which denotes the durability and stability of fibers to consecutive excitations. As so these one-dimensional photonic fibers made using cheap methods is of great importance for organic optoelectronic applications, fluorescent clothing or counterfeiting labels.

Soares, Í., J. Faria, A. Marques, I. A. C. Ribeiro, C. Baleizão, A. Bettencourt, I. Ferreira, and A. C. Baptista, "Drug Delivery from PCL/Chitosan Multilayer Coatings for Metallic Implants", ACS omega, vol. 7, pp. 23096-23106, 2022.
Esteves, C., G. M. C. Santos, C. Alves, S. I. C. J. Palma, A. R. Porteira, H. M. A. Costa, V. D. Alves, B. M. M. Faustino, I. Ferreira, and H. Gamboa, "Effect of film thickness in gelatine hybrid gels for artificial olfaction", Materials Today Bio, vol. 1, pp. 100002, 2019.
Soares, P. I. P., A. M. R. Alves, L. C. J. Pereira, J. T. Coutinho, I. M. M. Ferreira, C. M. M. Novo, and J. P. M. R. Borges, "Effects of surfactants on the magnetic properties of iron oxide colloids", J. Colloid Interface Sci., vol. 419, pp. 46-51, 2014. AbstractDOI

Iron oxide nanoparticles are having been extensively investigated for several biomedical applications such as hyperthermia and magnetic resonance imaging. However, one of the biggest problems of these nanoparticles is their aggregation.

Taking this into account, in this study the influence of three different surfactants (oleic acid, sodium citrate and Triton X-100) each one with various concentrations in the colloidal solutions stability was analyzed by using a rapid and facile method, the variation in the optical absorbance along time.

The synthesized nanoparticles through chemical precipitation showed an average size of 9 nm and a narrow size distribution. X-ray diffraction pattern and Fourier Transform Infrared analysis confirmed the presence of pure magnetite. SQUID measurements showed superparamagnetic properties with a blocking temperature around 155 K. In addition it was observed that neither sodium citrate nor Triton X-100 influences the magnetic properties of the nanoparticles. On the other hand, oleic acid in a concentration of 64 mM decreases the saturation magnetization from 67 to 45 emu/g. Oleic acid exhibits a good performance as stabilizer of the iron oxide nanoparticles in an aqueous solution for 24 h, for concentrations that lead to the formation of the double layer.

Muelle, H., P. Barquinha, I. Ferreira, E. Fortunato, M. C. Santos, and M. S. Diniz, "Effects of ultra-sonication on the cyanobacteria Microcystis aeruginosa structure and growth", Microsc. Microanal., vol. 21, pp. 50-51, 2015. AbstractDOI

The eutrophication of surface waters caused by cyanobacteria is a worldwide problem, leading to expensive
water treatment costs [1]. In addition, the production of microcystins by these microalgae may cause many
health problems to humans and animals (e.g. liver cancer) and even death [2]. Therefore, a variety of
methods have been developed to control cyanobacteria blooms, including physical and chemical treatments.
However, they have negative impacts on other species of (micro) algae and on other aquatic biota. As a
consequence, ultrasonic algae treatment has been proposed as a clean approach to controlling the blooms of
some algae species and microcystins degradation [3]. Still, the specific effects of ultra-sonication on
cyanobacteria are not well known. The present work aimed to study the effects of ultra-sonication on the
cyanobacteria structure under different ultrasound conditions (changing frequency and power) by using
conventional histology and electron microscopy methods.
Microcystis spp. were harvested in a lake from Azores (Portugal) and stored in the cool and dark until
transported to the laboratory. Cyanobacteria were cultured in liquid BG-11 axenic medium at 22ºC in an
incubator chamber, under continuous illumination (fluorescent cold white light).
Samples were collected and suspensions of cells (1ml each) were subjected to ultrasonic irradiation using
diverse ultrasonic equipment (UP100H; UP200S, sonoreactor UTR 200 and ultrasonic bath) and testing
different exposure times. All the experimental algal suspensions were exposed for 5 min to ultrasonication
(on ice for periods of 10s to avoid heating). After ultrasonication cyanobacteria growth was assessed for a
period of 14 days and structural changes in cells were evaluated by light (LM) and scanning electron
microscopy (SEM) examination. The results show growth inhibition of the cyanobacteria according to
intensity and power used in each ultrasonic device. The use of the most powerful devices (sonoreactor and
UP200S) resulted in a massive disrupting of cell walls with consequent cell death (Fig. 1e,f). Similar results
were obtained by Ahan et al. [1] and Nakano et al. [4] and showing cell wall disruption. However, even
after exposure to the most powerful instrumentation it was possible to detect some viable cells and after 14
days colonies were already visible. The results from light and electron microscopy showed noticeable
changes at the structural level such as disruption of cell gas vacuoles (arrowhead), colony disaggregation and
damage of cell walls of cells (Fig. 1c-f).
As a consequence, the use of ultrasounds to improve water quality from eutrophic waters must be considered
with careful in terms of efficiency and other complementary methods should be considered to assure good
water quality criteria. In addition, the effects of ultrasonication in other aquatic organisms require further
studies before using this technology to control algae blooms.

Baptista, A. C., M. Brito, A. Marques, and I. Ferreira, "Electronic control of drug release from gauze or cellulose acetate fibres for dermal applications", Journal of Materials Chemistry B, vol. 9, pp. 3515-3522, 2021.
Sousa, D. M., L. Cerqueira, A. Marques, G. Gaspar, J. C. Lima, and I. Ferreira, "Facile Microwave-assisted Synthesis Manganese Doped Zinc Sulfide Nanoparticles", Scientific Reports, vol. 8, pp. 15992, 2018.