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2005
Kuhn, FE, Zhao J, Abrantes M, Sun W, Afonso CAM, Branco LC, Goncalves IS, Pillinger M, Romao CC.  2005.  Catalytic olefin epoxidation with cyclopentadienyl-molybdenum complexes in room temperature ionic liquids. Tetrahedron Letters. 46:47-52., Number 1 AbstractWebsite
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da Silva, PF, Lima JC, Freitas AA, Shimizu K, Macanita AL, Quina FH.  2005.  Charge-transfer complexation as a general phenomenon in the copigmentation of anthocyanins. Journal of Physical Chemistry a. 109:7329-7338., Number 32 Abstract
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Branco, LC, Serbanovic A, da Ponte MN, Afonso CAM.  2005.  Clean osmium-catalyzed asymmetric dihydroxylation of olefins in ionic liquids and supercritical CO2 product recovery. Chemical Communications. :107-109., Number 1 AbstractWebsite
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Palma, LB, Coito FV, da Silva RN.  2005.  Combined approach to fault diagnosis based on principal components and influence matrix. Intelligent Signal Processing, 2005 IEEE International Workshop on. :171–176.: IEEE Abstract

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Figueirinhas, JL, Cruz C, Filip D, Feio G, Ribeiro AC, Frere Y, Meyer T, Mehl GH.  2005.  Deuterium NMR investigation of the biaxial nematic phase in an organosiloxane tetrapode. Phys Rev Lett. 94:107802., Number 10 AbstractWebsite

Deuterium NMR is used to examine the molecular order exhibited by an organosiloxane tetrapode giving the first experimental evidence, using a bulk sample, for the existence of a biaxial nematic phase in this type of compounds. The temperature dependence of the averaged quadrupolar coupling constant and asymmetry parameter was determined in the compound's nematic phase. Two distinct regimes could be identified, one with a vanishing asymmetry parameter corresponding to a uniaxial nematic phase and another with a significant temperature dependent asymmetry parameter, corresponding to a biaxial nematic phase. The high values obtained for the asymmetry parameter at the lower end of the nematic range are well above experimental error and constitute a definite proof of the biaxial nature of the nematic phase exhibited by the studied compound for those temperatures.

BRITO PALMA, L, Coito FV, NEVES DA SILVA R.  2005.  Diagnosis of parametric faults based on identification and statistical methods. Decision and Control, 2005 and 2005 European Control Conference. CDC-ECC’05. 44th IEEE Conference on. :3838–3843.: IEEE Abstract

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Noronha, MC, Lima JC, Santos H, Macanita AL.  2005.  The discrimination of tyrosine residues in ribonuclease A by picosecond time-resolved fluorescence spectroscopy. Febs Journal. 272:382. Abstract
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Pinto, I, Alves LB, Ortigueira MD, A.G. B.  2005.  ECG Wave Detection and Delineation with Wavelets. Computational Intelligence in Medicine and Healthcare Conference. : Biopattern Abstract
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Gago, S, Fernandes JA, Rainho JP, Ferreira RAS, Pillinger M, Valente AA, Santos TM, Carlos LD, Ribeiro-Claro PJA, Goncalves IS.  2005.  Highly luminescent tris(beta-diketonate)europium(III) complexes immobilized in a functionalized mesoporous silica. Chemistry of Materials. 17:5077-5084., Number 20 AbstractWebsite
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Gago, S, Pillinger M, Ferreira RAS, Carlos LD, Santos TM, Goncalves IS.  2005.  Immobilization of lanthanide ions in a pillared layered double hydroxide. Chemistry of Materials. 17:5803-5809., Number 23 AbstractWebsite
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Carvalho, AL, Pires VMR, Gloster TM, Turkenburg JP, Prates JAM, Ferreira LMA, Romao MJ, Davies GJ, Fontes C, Gilbert HJ.  2005.  Insights into the structural determinants of cohesin dockerin specificity revealed by the crystal structure of the type II cohesin from Clostridium thermocellum SdbA. Journal of Molecular Biology. 349:909-915., Number 5 AbstractWebsite
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Inácio, JA, Gerald JA, Ortigueira M.  2005.  New PN Even Balanced Sequences for spread spectrum systems. EURASIP Journal on Wireless Communications and Networking. 2005:447–458., Number 3: Hindawi AbstractWebsite
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Aucejo, R, Alarcon J, Garcia-Espana E, Llinares JM, Marchin KL, Soriano C, Lodeiro C, Bernardo MA, Pina F, Pina J, de Melo JS.  2005.  A new Zn-II tweezer pyridine-naphthalene system - An off-on-off system working in a biological pH window. European Journal of Inorganic Chemistry. :4301-4308., Number 21 AbstractWebsite
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Boer, DR, Muller A, Fetzner S, Lowe DJ, Romao MJ.  2005.  On the purification and preliminary crystallographic analysis of isoquinoline 1-oxidoreductase from Brevundimonas diminuta 7. Acta Crystallographica Section F-Structural Biology and Crystallization Communications. 61:137-140. AbstractWebsite
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Schafer, T, Branco LC, Fortunato R, Izak P, Rodrigues CM, Afonso CAM, Crespo JG.  2005.  Opportunities for membrane separation processes using ionic liquids. Ionic Liquids Iiib: Fundamentals, Progress, Challenges and Opportunities: Transformations and Processes. 902(Rogers, R. D., Seddon, K. R., Eds.).:97-110. Abstract
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Serbanovic, A, Branco LC, da Ponte MN, Afonso CAM.  2005.  Osmium catalyzed asymmetric dihydroxylation of methyl trans-cinnamate in ionic liquids, followed by supercritical CO2 product recovery. Journal of Organometallic Chemistry. 690:3600-3608., Number 15 AbstractWebsite
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Palma, LB, Coito FV, da Silva RN.  2005.  Process fault diagnosis approach based on neural observers. Emerging Technologies and Factory Automation, 2005. ETFA 2005. 10th IEEE Conference on. 1:4–pp.: IEEE Abstract

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Faria, TQ, Lima JC, Bastos M, Macanita AL, Santos H.  2005.  Protein stabilization by osmolytes from hyperthermophiles: effect of mannosylglycerate on the thermal unfolding of sthaplylicoccal nuclease studied by picosecond. Febs Journal. 272:352. Abstract
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Lopez-Cortes, A, Bursakov S, Figueiredo A, Thapper AE, Todorovic S, Moura JJ, Ollivier B, Moura I, Fauque G.  2005.  Purification and preliminary characterization of tetraheme cytochrome c3 and adenylylsulfate reductase from the peptidolytic sulfate-reducing bacterium Desulfovibrio aminophilus DSM 12254. Bioinorg Chem Appl. :81-91. AbstractWebsite

Two proteins were purified and preliminarily characterized from the soluble extract of cells (310 g, wet weight) of the aminolytic and peptidolytic sulfate-reducing bacterium Desulfovibrio (D.) aminophilus DSM 12254. The iron-sulfur flavoenzyme adenylylsulfate (adenosine 5'-phosphosulfate, APS) reductase, a key enzyme in the microbial dissimilatory sulfate reduction, has been purified in three chromatographic steps (DEAE-Biogel A, Source 15, and Superdex 200 columns). It contains two different subunits with molecular masses of 75 and 18 kDa. The fraction after the last purification step had a purity index (A(278nm) / A(388nm)) of 5.34, which was used for further EPR spectroscopic studies. The D. aminophilus APS reductase is very similar to the homologous enzymes isolated from D. gigas and D. desulfuricans ATCC 27774. A tetraheme cytochrome c(3) (His-heme iron-His) has been purified in three chromatographic steps (DEAE- Biogel A, Source 15, and Biogel-HTP columns) and preliminarily characterized. It has a purity index ([A(553nm) - A(570nm)](red) / A(280nm)) of 2.9 and a molecular mass of around 15 kDa, and its spectroscopic characterization (NMR and EPR) has been carried out. This hemoprotein presents similarities with the tetraheme cytochrome c(3) from Desulfomicrobium (Des.) norvegicum (NMR spectra, and N-terminal amino acid sequence).

BRITO PALMA, L, VIEIRA COITO F, NEVES DA SILVA R.  2005.  Robust fault diagnosis approach using analytical and knowledge based techniques applied to a water tank system. : CRL Abstract

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Costa, T, Miguel MG, Lindman B, Schillen K, Lima JC, de Melo JS.  2005.  Self-assembly of a hydrophobically modified naphthalene-labeled poly(acrylic acid) polyelectrolyte in water: Organic solvent mixtures followed by steady-state and time-resolved fluorescence. Journal of Physical Chemistry B. 109:3243-3251., Number 8 Abstract
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Coito, F, Almeida P, Palma LB.  2005.  SMCRVI-a Labview/Matlab based tool for remote monitoring and control. Emerging Technologies and Factory Automation, 2005. ETFA 2005. 10th IEEE Conference on. 2:6–pp.: IEEE Abstract

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Coito, F, Lemos JM, Alves SS.  2005.  Stochastic Extremum Seeking in the Presence of Constraints. World Congress. 16:266–266., Number 1 Abstract

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Santos-Silva, T, Trincao J, Carvalho AL, Bonifacio C, Auchere F, Moura I, Moura JJG, Romao MJ.  2005.  Superoxide reductase from the syphilis spirochete Treponema pallidum: crystallization and structure determination using soft X-rays. Acta Crystallographica Section F-Structural Biology and Crystallization Communications. 61:967-970. AbstractWebsite
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Gago, S, Rodriguez-Borges JE, Teixeira C, Santos AM, Zhao J, Pillinger M, Nunes CD, Petrovski Z, Santos TM, Kuhn FE, Romao CC, Goncalves IS.  2005.  Synthesis, characterization and catalytic studies of bis(chloro)dioxomolybdenum(VI)-chiral diimine complexes. Journal of Molecular Catalysis a-Chemical. 236:1-6., Number 1-2 AbstractWebsite
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