Preparation and liquid-crystalline properties of toluene-4-sulphonyl urethane of hydroxypropylcellulose

Godinho, Maria Helena, João Paulo Borges, João Carlos Bordado, Maria Teresa Cidade, and Assis Farinha Martins. "Preparation and liquid-crystalline properties of toluene-4-sulphonyl urethane of hydroxypropylcellulose." Liquid Crystals 14 (1993): 653-659.


A novel liquid-crystalline polymer, the toluene-4-sulphonyl urethane of hydroxypropylcellulose (TSUHPC), was prepared through chemical modification of hydroxypropylcellulose (HPC) of Mw = 60000 g mol−1. The resulting polymer was characterized by infrared spectroscopy, differential scanning calorimetry (DSC) and polarizing microscopy. It was found that thermotropic liquid crystal phases are formed between about 60°C and 110°C. Concentrated solutions of TSUHPC in acetone and N,N-dimethylacetamide exhibit cholesteric behaviour, at room temperature. When approaching the lyotropic mesophase to solid transition, either by cooling or by solvent evaporation, very interesting arborescent structures of a seemingly fractal nature may be observed, depending on the kinetics of the transition. A banded texture can be observed when the polymer is sheared near the transition to the isotropic phase.

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