Publications

2018

Vânia Castro, Rita Craveiro, Joana Silva, Rui L. Reis, Alexandre Paiva, Ana Rita Cruz Duarte, Natural deep eutectic systems as alternative nontoxic cryoprotective agents, Cryobiology, (2018) 83, 15 - 26. DOI: 10.1016/j.cryobiol.2018.06.010


Ribeiro, Helena; Allegro, Margherita; Marto, Joana; Pedras, Bruno; Oliveira, Nuno G.; Paiva, Alexandre; Barreiros, Susana; Goncalves, Lidia M. D., Simões, Pedro, Converting spent coffee grounds into bioactive extracts with potential skin anti-aging and lightening effects, ACS Sustainable Chemistry & Engineering, (2018), 6 (5), 6289 – 6295. DOI: 10.1021/acssuschemeng.8b00108


Alexandre Paiva, Ana Matias, Ana Rita Cruz Duarte, How do we drive deep eutectic systems towards an industrial reality?, Current Opinion in Green and Sustainable Chemistry, (2018), 11, 81 – 85. DOI: 10.1016/j.cogsc.2018.05.010


Joana M.Silva, Rui L. Reis, Alexandre Paiva, Ana Rita C. Duarte, Design of Functional Therapeutic Deep Eutectic Solvents Based on Choline Chloride and Ascorbic Acid, ACS Sustainable Chemistry & Engineering, (2018), 6(8), 10355 – 10363. DOI: 10.1021/acssuschemeng.8b01687


Vânia I. B. Castro, Francisca Mano, Margarida S. Miranda, Rui L. Reis, Alexandre Paiva, Ana Rita C. Duarte*, Synthesis and Physical and Thermodynamic Properties of Lactic Acid and Malic Acid-Based Natural Deep Eutectic Solvents, Journal of Chemical and Engineering Data, (2018), 63(7), 2548 – 2556. DOI: 10.1021/acs.jced.7b01037


Alexandre Paiva, Karen Ranocchia, Marisa Marques, Marco Gomes da Silva, Vítor Alves, Isabel Coelhoso*, Pedro Simões, Concentration of coffee extracts by osmotic evaporation: effect on antioxidant activity and aroma profile, Journal of Food Engineering, (2018), 222, 178 - 184, doi:10.3390/membranes7010001



2017

ARR Pinto, F Antas, RCD Santos, S Bowra, P Simões, S Barreiros, A Paiva, 2017. Effect of reactor configuration on the subcritical water hydrolysis of recycled paper mill sludge. Journal of Analytical and Applied Pyrolysis 127, 68-74; doi.org/10.1016/j.jaap.2017.08.021

B Pedras, M Salema-Oom, I Sá-Nogueira, P Simões, A Paiva, S Barreiros, 2017. Valorization of white wine grape pomace through application of subcritical water: Analysis of extraction, hydrolysis, and biological activity of the extracts obtained. The Journal of Supercritical Fluids 128, 138-144; doi.org/10.1016/j.supflu.2017.05.020

ASD Ferreira, S Barreiros, EJ Cabrita, 2017. Probing sol-gel matrices microenvironments by PGSE HR-MAS NMR, Magnetic Resonance in Chemistry 55, 452-463; doi.org/10.1002/mrc.4427

AC Trindade, R Craveiro, APC Almeida, JP Canejo, A Paiva, S Barreiros, MH Godinho, 2017. Tuning Surface Wrinkles of Janus Spheres in supercritical carbon dioxide, J Supercrit Fluid 120, 125-131; doi.org/10.1016/j.supflu.2016.06.019

ARC Duarte, ASD Ferreira, S Barreiros, E Cabrita, RL Reis, A Paiva, 2017. A comparison between pure active pharmaceutical ingredients and therapeutic deep eutectic solvents: Solubility and permeability studies, Eur J Pharm Biopharm 114, 296-304; doi.org: 10.1016/j.ejpb.2017.02.003

S Rebocho, AVM Nunes, V Najdanovic-Visak, S Barreiros, A Paiva, 2017. Experimental Determination and Modeling of the Phase Behavior of the CO2 + Propionic Anhydride Binary System at High Pressure, J Chem Eng Data 62, 210-213; DOI: 10.1021/acs.jced.6b00595

F Mano, M Martins, I Sá-Nogueira, S Barreiros, JP Borges, RL Reis, ARC Duarte, A Paiva, 2017. Production of Electrospun Fast-Dissolving Drug Delivery Systems with Therapeutic Eutectic Systems Encapsulated in Gelatin, AAPS Pharm Sci Tech 18, 2579-2585; doi: 10.1208/s12249-016-0703-z

T Cordeiro, C Castineira, D Mendes, F Danède, J Sotomayor, IM Fonseca, M Gomes da Silva, A Paiva, BS arreiros, MM Cardoso, MT Viciosa, NT Correia, M Dionisio, 2017 Stabilizing Unstable Amorphous Menthol through Inclusion in Mesoporous Silica Hosts, Mol Pharm 14, 3164-3177; DOI: 10.1021/acs.molpharmaceut.7b00386

A. Gertrudes, I. Aroso, Z. Eltayari, R. Reis, A. Paiva, A. Duarte, How Do Animals Survive Extreme Temperature Amplitudes? The Role of Natural Deep Eutectic Solvents, sustainable chemistry & engineering, (2017), 5(11), 9542 – 9553. Doi: 10.1021/acssuschemeng.7b01707  

Ivo M. Aroso, Alexande Paiva, Rui L. Reis and Ana R. C. Duarte, Natural deep eutectic solvents from choline chloride and betaine – physicochemical properties, Journal of Molecular Liquids, (2017), 241, 654 – 661, DOI: 10.1016/j.molliq.2017.06.051

Alexandre Barros, Rita Craveiro, Rui Reis, Alexandre Paiva, Joana Silva, Ana Duarte, Green solvents for enhanced impregnation processes in biomedicine, Current Opinion in Green and Sustainable Chemistry, (2017), 5, 82 – 87, DOI: 10.1016/j.cogsc.2017.03.014
2016

R Craveiro, I Aroso, V Flammia, T Carvalho, MT Viciosa, M Dionísio, S Barreiros, RL Reis, ARC Duarte, A Paiva, 2016. Properties and thermal behavior of natural deep eutectic solvents, J Mol Liq 215, 534-540; doi.org/10.1016/j.molliq.2016.01.038

J Marto, LF Gouveia, BG Chiari, A Paiva, V Isaac, P Pinto, P Simões, AJ Almeida, HM Ribeiro, 2016. The green generation of sunscreens: Using coffee industrial sub-products. Industrial Crops and Products 80, 93-100; dx.doi.org/10.1016/j.indcrop.2015.11.033.

J del Valle, A Bejarano, PC Simoes, 2016. Fractionation technologies for liquid mixtures using dense carbon dioxide. J. Supercritical Fluids 107, 321-348; dx.doi.org/10.1016/j.supflu.2015.09.021

IM Aroso, JC Silva, F Mano, ASD Ferreira, M Dionísio, I Sá-Nogueira, S Barreiros, RL Reis, A Paiva, ARC Duarte, 2016. Dissolution enhancement of active pharmaceutical ingredients by therapeutic deep eutectic systems, Eur J Pharm Biopharm 98, 57-66; doi: 10.1016/j.ejpb.2015.11.002

2015
M Gameiro, P Lisboa, A Paiva, S Barreiros, P Simões*, 2015. Supercritical carbon dioxide-based integrated continuous extraction of oil from chicken feather meal, and its conversion to biodiesel in a packed-bed enzymatic reactor, at pilot scale. Fuel 153, 135-142; dx.doi.org/10.1016/j.fuel.2015.02.100


R Couto, L Neves, P Simões, I Coelhoso, 2015. Supported Ionic Liquid Membranes and Ion-Jelly® Membranes with [BMIM][DCA]: Comparison of Its Performance for CO2 Separation. Membranes 5(1), 13-21; doi:10.3390/membranes5010013


F Mano, IM Aroso, S Barreiros, JP Borges, RL Reis, ARC Duarte, A Paiva, 2015. Production of Poly(vinyl alcohol) (PVA) Fibers with Encapsulated Natural Deep Eutectic Solvent (NADES) Using Electrospinning, ACS Sustainable Chem Eng 3, 2504-2509; DOI: 10.1021/acssuschemeng.5b00613


IM Aroso, R Craveiro, A Rocha, M Dionísio, S Barreiros, RL Reis, A Paiva, ARC Duarte, 2015. Design of controlled release systems for THEDES—Therapeutic deep eutectic solvents, using supercritical fluid technology, Int J Pharm 492, 73-79; doi.org/10.1016/j.ijpharm.2015.06.038


Madalena V. Cruz, Filomena Freitas, Alexandre Paiva, Francisca Mano, Madalena Dionísio, Ana Maria Ramos, Maria A. M. Reis, “Valorisation of fatty acids-containing wastes and byproducts into short- and medium-chain length polyhydroxyalkanoates”, N. Biotechnol.(2016), 33 (1), 206 - 215, DOI: 10.1016/j.nbt.2015.05.005.


2014

RM Couto, C Lourenço, PC Simões, LC Branco, 2014. Task specific Ionic liquids as polarity shifting additives of common organic solvents. New Journal of Chemistry 38, 5559-5565; DOI: 10.1039/C4NJ00781F

PI Morgado, PF Lisboa, MP Ribeiro, SP Miguel, PC Simões, IJ Correia, A Aguiar-Ricardo, 2014. Poly(vinylalcohol) / chitosan asymmetric membranes: highly controlled morphology toward the ideal wound dressing. Journal of Membrane Science 469, 262–271, DOI: 10.1016/j.memsci.2014.06.035

S Rebocho, AVM Nunes, V Najdanovic-Visak, S Barreiros, P Simões, A Paiva, 2014. High pressure vapor-liquid equilibrium for the ternary system ethanol/(±)-menthol /carbon dioxide. J. Supercritical Fluids 92, 282–287, DOI: 10.1016/j.supflu.2014.06.006

A Rocha, NMT Lourenço, P Vidinha, P Simões, A Paiva, 2014. Separation of free fatty acids from deodorizer distillates using choline hydrogen carbonate and supercritical carbon dioxide. Separation and Purification Technology 131, 14-18, dx.doi.org/10.1016/j.seppur.2014.03.009

MV da Cruz, A Paiva, P Lisboa, F Freitas, V Alves, P Simões, S Barreiros, MAM Reis, 2014. Production of polyhydroxyalkanoates from spent coffee grounds oil obtained by supercritical fluid extraction technology. Bioresource Technology 157, 360–363, dx.doi.org/10.1016/j.biortech.2014.02.013

P Lisboa, AR Rodrigues, JL Martín, P Simões, S Barreiros, A Paiva, 2014. Economic analysis of a plant for biodiesel production from waste cooking oil via enzymatic transesterification using supercritical carbon dioxide. J. Supercritical Fluids 85, 31-40, DOI: 10.1016/j.supflu.2013.10.018

R Craveiro, M Martins, GB Santos, N Correia, M Dionísio, S Barreiros, ARC Duarte, RL Reis, A Paiva, 2014. Starch-based polymer-IL composites formed by compression moulding and supercritical fluid foaming for self-supported conductive material, RSC Adv 4, 17161; doi: 10.1039/C4RA01424C

G Barreira, ASD Ferreira, P Vidinha, JMS Cabral, JMG Martinho, JC Lima, EJ Cabrita, S Barreiros, 2014. Assessing diffusion in enzyme loaded sol–gel matrices, RSC Adv 4, 25099-25105; doi: 10.1039/C4RA01620C

T Carvalho, V Augusto, A Rocha, N Lourenço, N Correia, S Barreiros, P Vidinha, E Cabrita, M Dionísio, 2014. Ion Jelly Conductive Properties Using Dicyanamide Based Ionic Liquids, J Phys Chem B 118, 9445-9459; DOI: 10.1021/jp502870q

Marta Martins, Ivo Aroso, Rita Craveiro, Rui L. Reis, Alexandre Paiva, Ana Rita C. Duarte, “Enhanced performance of supercritical fluid foaming of natural-based polymers by deep eutectic solvents”, AIChe Journal, (2014), 60(11), 3701 – 3706, DOI: 10.1002/aic.14607

Alexandre Paiva, Rita Craveiro, Ivo Aroso, Marta Martins, Rui L. Reis, Ana Rita C. Duarte, Natural Deep Eutectic Solvents – Solvents for the 21st century, sustainable chemistry & engineering, (2014), 2, 1063 – 1071, DOI: 10.1021/sc500096j (journal cover paper)

Cristiana Morais, Madalena V. Cruz, Alexandre Paiva, Madalena Dionísio, Filomena Freitas*, Maria A.M. Reis , Conversion of fat-containing waste from the  margarine manufacturing  process into bacterial  polyhydroxyalkanoates, International Journal of Biological Macromolecules (2014), 71, 68 - 73

M. Martins, Rita Craveiro, Alexandre Paiva, Ana Rita C. Duarte, Rui L. Reis, Supercritical fluid processing of natural based polymers doped with ionic liquids, Chemical Engineering Journal, (2014), 241, 122 – 130, DOI: 10.1016/j.cej.2013.11.080