Citation:

Probing the iron environment in desulforedoxin. EXAFS of oxidized and reduced states, Stalhandske, CMV, Dong J., Tavares P., Liu M. Y., Legall J., Moura J. J. G., Moura I., Park J. B., Adams M. W. W., and Scott R. A. , INORGANICA CHIMICA ACTA, Volume {273}, Number {1-2}, p.{409-411}, (1998) copy at https://sites.fct.unl.pt/molecular-biophysics/publications/probing-iron-environment-desulforedoxin-exafs-oxidized-and-reduced

Abstract:

Fe XAS data were collected on the oxidized and reduced forms of desulforedoxin from Desulfovibrio gigas, the oxidized form of rubredoxin from Clostridium pasteurianum, and the reduced form of rubredoxin from Pyrococcus furiosus. Analysis of these data is consistent with tetrahedral FeS(4) coordination in both oxidation states, and an expansion of the Fe-S distances from 2.27 to 2.33 Angstrom upon reduction. (C) 1998 Elsevier Science S.A. All rights reserved.

Notes:

33rd International Conference on Coordination Chemistry, FLORENCE, ITALY, AUG 30-SEP 04, 1998