Hydrogen production and deuterium-proton exchange reactions catalyzed by Desulfovibrio nickel(II)-substituted rubredoxins

Citation:
Hydrogen production and deuterium-proton exchange reactions catalyzed by Desulfovibrio nickel(II)-substituted rubredoxins, Saint-Martin, P., Lespinat P. A., Fauque G., Berlier Y., Legall J., Moura I., Teixeira M., Xavier A. V., and Moura J. J. , Proc Natl Acad Sci U S A, Dec, Volume 85, Number 24, p.9378-80, (1988)

Abstract:

The nickel tetrahedral sulfur-coordinated core formed upon metal replacement of the native iron in Desulfovibrio sp. rubredoxins is shown to mimic the reactivity pattern of nickel-containing hydrogenases with respect to hydrogen production, deuterium-proton exchange, and inhibition by carbon monoxide.

Notes:

0027-8424 (Print)0027-8424 (Linking)Journal Article

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