@article {2412,
	title = {Electronic structure description of the mu(4)-sulfide bridged tetranuclear Cu(Z) center in N(2)O reductase},
	journal = {J Am Chem Soc},
	volume = {124},
	number = {5},
	year = {2002},
	note = {<p>0002-7863 (Print)0002-7863 (Linking)Journal ArticleResearch Support, Non-U.S. Gov{\textquoteright}tResearch Support, U.S. Gov{\textquoteright}t, Non-P.H.S.Research Support, U.S. Gov{\textquoteright}t, P.H.S.</p>
},
	month = {Feb 6},
	pages = {744-5},
	abstract = {<p>Spectroscopy coupled with density functional calculations has been used to define the spin state, oxidation states, spin distribution, and ground state wave function of the mu4-sulfide bridged tetranuclear CuZ cluster of nitrous oxide reductase. Initial insight into the electronic contribution to N2O reduction is developed, which involves a sigma superexchange pathway through the bridging sulfide.</p>
},
	keywords = {Circular Dichroism, Copper/*chemistry, Electron Spin Resonance Spectroscopy, Molecular Structure, Oxidoreductases/*chemistry, Spectrometry, X-Ray Emission/methods, Sulfides/*chemistry},
	url = {http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?cmd=Retrieve\&db=PubMed\&dopt=Citation\&list_uids=11817937 },
	author = {Chen, P. and DeBeer George, S. and Cabrito, I. and Antholine, W. E. and Moura, J. J. and Moura, I. and Hedman, B. and Hodgson, K. O. and Solomon, E. I.}
}
